Glucosyl anthranilate

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Glucosyl anthranilate

In the crystal structure of the title compound, C(21)H(25)NO(11), the hexopyranosyl ring adopts a chair conformation and the five substituents are in equatorial positions. An intra-molecular hydrogen bond between the amino group and a neighbouring carbonyl group is found. Two carbonyl groups are disordered and were refined using a split model.

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The reaction mixture of magnesium chloride with two equivalents of potassium anthranilate [K+ AnthÐ] in water gives on cooling to 0 ∞C a 60% yield of a precipitate which after drying in a vacuum has the composition [Mg(H2O)6](Anth)2 (1). Recrystallization from hot water affords an octahydrate identified as [Mg(H2O)6](Anth)2(H2O)2 (2) in a single crystal X-ray diffraction study. Contrary to find...

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Improved Synthesis of Glucosyl Esters

An improved synthesis of glucosyl esters was reported here, avoiding the use of expensive Ag reagent as well as the hydrolysis of instable glucosyl bromide. Notably, -configuration product was exclusively obtained in good yield.

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Anthranilate synthase-anthranilate 5-phosphoribosyl 1-pyrophosphate phosphoribosyltransferase from Aerobacter aerogenes.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809040975